trans-Dichloridobis[diphenyl(4-vinylphenyl)phosphane-κP]palladium(II)
نویسنده
چکیده
In the title compound, [PdCl(2)(C(20)H(17)P)(2)], the Pd(II) atom lies on a center of symmetry, resulting in a distorted trans-square-planar geometry. The Pd-P and Pd-Cl bond lengths are 2.3366 (7) and 2.2966 (7) Å, respectively. The vinyl group is disordered over two sets of sites in a 0.696 (15):0.304 (15) ratio.
منابع مشابه
trans-Dichloridobis[diphenyl(thiophen-2-yl)phosphane-κP]palladium(II)
The title compound, trans-[PdCl(2)(C(16)H(13)PS)(2)], forms a monomeric complex with a trans-square-planar geometry. The Pd-P bond lengths are 2.3387 (11) Å, as the Pd atom lies on an inversion point, while the Pd-Cl bond lengths are 2.2950 (12) Å.
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The title compound, [PdCl(2)(C(21)H(33)P)(2)], forms a monomeric complex with a trans-square-planar coordination geometry about the Pd(II) atom which lies on an inversion centre. The Pd-P bond lengths are 2.3760 (13) Å, while the Pd-Cl bond lengths are 2.3172 (14) Å. The observed structure was found to be closely related to that of trans-dichloridobis[dicyclo-hex-yl(phen-yl)phosphane-κP]palladi...
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The title compound, [PtCl(2)(C(20)H(17)P)(2)], forms a monomeric cis-square-planar geometry. The Pt-P bond lengths are 2.2489 (9) and 2.2627 (9) Å, whereas the Pt-Cl bond lengths are 2.3566 (9) and 2.3336 (9) Å.
متن کاملtrans-Dichloridobis(triphenylphosphane-κP)palladium(II) benzene hemisolvate
The title complex, [PdCl(2)(C(18)H(15)P)(2)]·0.5C(6)H(6), has the Pd(II) ion in a square-planar coordination mode (r.m.s. deviation for Pd, P and Cl atoms = 0.024 Å) with the PPh(3) and Cl ligands mutually trans. The benzene solvent mol-ecule is located about a crystallographic inversion centre. The title complex is isostructural with trans-dichloridobis(triphenyl-phosphane)-palladium(II) 1,4-d...
متن کاملtrans-Carbonylchloridobis[diphenyl(4-vinylphenyl)phosphane-κP]rhodium(I)
In the title compound, trans-[RhCl(C(20)H(17)P)(2)(CO)], the Rh(I) atom is situated on a center of symmetry, resulting in a statistical 1:1 disorder of the chloride [Rh-Cl = 2.383 (2) Å] and carbonyl [Rh-C = 1.752 (7) Å] ligands. The distorted trans square-planar environment is completed by two P atoms [Rh-P = 2.3251 (4) Å] from two diphen-yl(4-vinyl-phen-yl)phosphane ligands. The vinyl group i...
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